Small Diesel Spills (500-5000 gallons)

Number 6 Fuel Oil (Bunker C) Spills 

FACT SHEET: Small Diesel Spills (500-5000 gallons)

• Diesel fuel is a light, refined petroleum product with a relatively narrow boiling range, meaning that, when spilled on water, most of the oil will evaporate or naturally disperse within a few days or less. This is particularly true for typical spills from a fishing vessel (500-5,000 gallons), even in cold water. Thus, seldom is there any oil on the surface for responders to recover.
• When spilled on water, diesel oil spreads very quickly to a thin film. Even when the oil is described as a heavy sheen, it is 0.0004 inches thick and contains about 1,000 gallons per square nautical mile of continuous coverage. The volume of oil in areas covered by streamers would be much less. Silver sheen only contains about 75 gallons per square nautical mile.
• Diesel has a very low viscosity and is readily dispersed into the water column when winds reach 5-7 knots or sea conditions are 2-4 foot.
• Diesel oil is much lighter than water (specific gravity is about 0.85, compared to 1.03 for seawater). It is not possible for this oil to sink and accumulate on the seafloor as pooled or free oil.
• However, it is possible for the oil to be physically mixed into the water column by wave action, forming small droplets that are carried and kept in suspension by the currents.
• Oil dispersed in the water column can adhere to fine-grained suspended sediments which then settle out and get deposited on the seafloor. This process is more likely to occur near river mouths where fine-grained sediment are carried in by rivers. It is less likely to occur in open marine settings. This process is not likely to result in measurable sediment contamination for small spills.
• Diesel oil is not very sticky or viscous, compared to black oils. When small spills do strand on the shoreline, the oil tends to penetrate porous sediments quickly, but also to be washed off quickly by waves and tidal flushing. Thus, shoreline cleanup is usually not needed.
• Diesel oil is readily and completely degraded by naturally occurring microbes, under time frames of one to two months.
• In terms of toxicity to water-column organisms, diesel is considered to be one of the most acutely toxic oil types. Fish, invertebrates and seaweed that come in direct contact with a diesel spill may be killed. However, small spills in open water are so rapidly diluted that fish kills have never been reported. Fish kills have been reported for small spills in confined, shallow water.
• Crabs and shellfish can be tainted from small diesel spills in shallow, nearshore areas. These organisms bioaccumulate the oil, but will also depurate the oil, usually over a period of several weeks after exposure.
• Small diesel spills can affect marine birds by direct contact*, though the number of birds affected is usually small because of the short time the oil is on the water surface. Mortality is caused by ingestion during preening as well as to hypothermia from matted feathers. Experience with small diesel spills, is that few birds are directly affected. However, small spills could result in serious impacts to birds under the "wrong" conditions, such as a grounding right next to a large nesting colony or transport of sheens into a high bird concentration area.

NOAA/Hazardous Materials Response and Assessment Division

7600 Sand Point Way NE

Seattle, WA  98115

206/526-6317

FACT SHEET: No. 6 Fuel Oil (Bunker C) Spills

• No. 6 fuel oil is a heavy oil produced by blending heavy residual oils with a light oil (often No. 2 fuel oil) to meet specifications for viscosity and pour point.
• When spilled on water, No. 6 fuel spreads into thick slicks which can contain large amounts of oil. Oil recovery by skimmers and vacuum pumps can be very effective, particularly early in the spill.
• Very little of this viscous oil is likely to mix into the water column. It can form thick streamers or, under strong wind conditions, break into patches and tarballs.
• It is a persistent oil; only 5-10% is expected to evaporate within the first hours of a spill. Thus, spilled oil can be carried long distances by winds and currents. Previous bunker oil spills have contaminated shorelines over 200 miles from the spill site.
• The specific gravity of a particular No. 6 fuel oil can vary widely, from 0.95 to greater than 1.03. Thus, spilled oil can float, suspend in the water column, sink, or do all of these simultaneously, if the oil is poorly mixed. Floating slicks may become non-floating when they spread into areas of freshwater influence. 
• Floating oil could potentially sink once it strands on the shoreline, picks up sediment, and then is eroded by wave action.
• No. 6 fuel oil can be very viscous and sticky, meaning that stranded oil tends to remain on the surface rather than penetrate sediments. Light accumulations usually form a "bath-tub ring" at the high-tide line; heavy accumulations can pool on the surface.
• Shoreline cleanup can be very effective, particularly soon after the spill before the oil weathers, becoming stickier and even more viscous. Removal is needed because degradation rates for heavy oils are very slow, taking months to years.
• Adverse effects of floating No. 6 fuel oil are related primarily to coating of wildlife dwelling on the water surface, smothering of intertidal organisms, and long-term sediment contamination. No. 6 fuel oil is not expected to be as acutely toxic to water column organisms as lighter oils, such as No. 2 fuel oil.
• Direct mortality rates can be high for seabirds, waterfowl, and fur-bearing marine mammals, especially where populations are concentrated in small areas, such as during bird migrations or marine mammal haulouts. *
• Direct mortality rates are generally less for shorebirds because they rarely enter the water. Shorebirds, which feed in intertidal habitats where oil strands and persists, are at higher risk of sublethal effects from either contaminated or reduced population of prey.
• The most important factors determining the impacts of No. 6 fuel oil contamination on marshes are the extent of oiling on the vegetation and the degree of sediment contamination from the spill or disturbance from the cleanup. Many plants can survive partial oiling; fewer survive when all or most of the above-ground vegetation is coated with heavy oil. However, unless the substrate is heavily oiled, the roots often survive and the plants can re-grow.

NOAA/Hazardous Materials Response and Assessment Division

7600 Sand Point Way NE

Seattle, WA  98115

206/526-6317

P.O.L. Sorb Products Reduces Damaging Effects on Wildlife

Fuel spills on water can quickly damage safety conditions for indiginous wildlife.  However, when P.O.L. Sorb is used to contain fuels on water, wildlife will not suffer oily coats and other damaging effects when they come into contact with the spent absorbent.

This is due to the very nature of the P.O.L. Sorb product performance of encapsulating the oils it comes into contact with.

Contact protectwildlife@arkent.com for further information.